Contents

Transportation Industry
The Practical Guide to Surface Science (2026)

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Written by
Dr Amit Pratap Singh
PhD, Delhi University Post Doc - AIST Japan
Guest Author
Read More
alidad
Reviewed by
Dr Alidad Amirfazli
Dr. Amirfazli, a leading expert in surface wetting and superhydrophobic coatings, has 250+ publications, edits Advances in Colloid and Interface Science, and has received multiple research awards.
Scientific Advisor & Co-founder
Read More
D54c15105cfe94f786c500e4091d6ea65457608fde49ba183c8f862814a54249?s=100&d=m
Written By

Dr Amit Pratap Singh

Guest Author

PhD, Delhi University

Post Doc - AIST Japan

alidad
Reviewed By

Dr Alidad Amirfazli

Scientific Advisor & Co-founder

Dr. Amirfazli, a leading expert in surface wetting and superhydrophobic coatings, has 250+ publications, edits Advances in Colloid and Interface Science, and has received multiple research awards.

This is a practical guide to Surface Science for researchers working in the Transportation Industry.

In this all-new guide you’ll learn all about:

  • Crucial surface science principles
  • The significance of surface science measurements for the Transportation industry
  • Applicable ASTM Standards & Guidelines

Let’s dive right in.

Cargo ship on the river

Executive Summary

What it covers: How transport engineers use contact angle, dynamic contact angle, sliding angle and surface tension on coatings, metal surfaces and battery materials. Each topic links to a use case or a standard.
Key insights: A high contact angle shows that a surface repels water, but not that drops will run off. Sliding angle and contact angle hysteresis answer that second question, which matters for rain, spray and ice.
Business value: Ranking coatings and surface treatments on flat coupons narrows the field before costly rig and road testing. A wetting check before bonding catches poor surface preparation while the part can still be cleaned again.
Standards to follow: ISO 19403-6 describes dynamic contact angle by changing drop volume, giving advancing and receding angles and hysteresis. ISO 19403-7 describes roll off angle on a tilt stage. Neither sets pass limits, so build them from your own parts.
Bottom line: Measure both contact angle and sliding angle when a surface must shed water or ice. Start with the coating or bond that fails most often, then book a 15 minute demo to try it on your own coupons.

Chapter 1: Introduction

In transportation, many coating and bonding problems come down to how water and other liquids meet a surface. A repellent coating that beads water but holds drops in place does not clear. A bond on a poorly prepared metal surface can fail after assembly.

These are the places where wetting decides yield in transportation work:

  • Rain repellent glass. Contact angle, sliding angle and hysteresis show whether a windshield coating still clears water after wiper and washer wear. See windshield rain repellent performance.
  • Aluminum bonding. Water contact angle at a fixed time after surface preparation flags oxide drift and contamination before the adhesive goes on. See reliable aluminum bonding.
  • Battery electrolyte wetting. Electrolyte surface tension and contact angle on separators and electrodes help rank additives before cell builds. See electrolyte and separator wetting.

The Dropometer drop shape analysis kit measures contact angle, surface and interfacial tension, surface free energy and sliding angle with one portable setup. Its method was validated against a KRUSS DSA100E in two peer reviewed papers. If you are new to the terms, start with wettability.

We use the following surface properties to understand the behavior of Transportation products and improve their quality.

Chapter 2: Contact Angle Measurement

The contact angle quantifies the wettability of a surface by representing the angle between a liquid’s surface and a solid surface.
Dropletlab Research

Sample Image taken from Droplet Lab Tensiometer.

Young – Laplace Method

Polynomial Method

Dynamic Contact Angle

Ideally, when we place a drop on a solid surface, a unique angle exists between the liquid and the solid surface. We can calculate the value of this ideal contact angle (the so-called Young’s contact angle) using Young’s equation. In practice, due to surface geometry, roughness, heterogeneity, contamination, and deformation, the contact angle value on a surface is not necessarily a single consistent value but rather falls within a range. The upper and lower limits of this range are known as the advancing and receding contact angles, respectively. The values of advancing and receding contact angles for a solid surface are highly sensitive to many parameters, such as temperature, humidity, homogeneity, and minor contamination of the surface and liquid. For example, the advancing and receding contact angles of a surface can differ at different locations.

Dynamic Contact Angle versus Static Contact Angle

Practical surfaces and coatings naturally show contact angle hysteresis, indicating a range of equilibrium values. When we measure static contact angles, we get a single value within this range. Solely relying on static measurements poses problems, like poor repeatability and incomplete surface assessment regarding adhesion, cleanliness, roughness, and homogeneity.

In practical applications, we need to understand how easily a liquid spreads (advancing angle) and how easily it is removed (receding angle), such as in painting and cleaning. Measuring advancing and receding angles offers a holistic view of liquid-solid interaction, unlike static measurements, which yield an arbitrary value within the range.

This insight is crucial for real-world surfaces with variations, roughness, and dynamics, aiding industries like cosmetics, materials science, and biotechnology in designing effective surfaces and optimizing processes.

Learn how Contact Angle measurement is done on our Tensiometer

For a more complete understanding of Contact Angle measurement, read our Contact Angle measurement: The Definitive Guide

Open Benchmark Data: Contact Angle & Surface Energy

These reference measurements show how deionized water wets four standard substrates measured with the Droplet Lab Dropometer. Use them as visual and numerical benchmarks when you're checking your own sample preparation, treatments, and chemistry.

Full contact angle and surface energy datasets (including additional liquids and statistics) are available on our dataset hub.

Glass - DI Water
Glass - DI Water
Nylon - DI Water
Nylon - DI Water
PMMA - DI Water
PMMA - DI Water
Teflon - DI Water
Teflon - DI Water

The droplet images above are taken from the same benchmark series as our open dataset. For each substrate and probe liquid we report:

● Advancing and receding contact angles (and hysteresis)
● Derived surface energy (SFE) values based on multi-liquid measurements
● Measurement conditions, uncertainties, and sample preparation details

Comparing your own droplet shapes and angles against these references is a fast way to spot contamination, treatment drift, or unexpected changes in wettability.

Chapter 3: Surface Tension Measurement

This property measures the force that acts on the surface of a liquid, aiming to minimize its surface area.

Surface Tension Measurement

Sample Image taken from Droplet Lab Tensiometer

Dynamic Surface Tension

Dynamic surface tension differs from static surface tension, which refers to the surface energy per unit area (or force acting per unit length along the edge of a liquid surface).

Static surface tension characterizes the equilibrium state of the liquid interface, while dynamic surface tension accounts for the kinetics of changes at the interface. These changes could involve the presence of surfactants, additives, or variations in temperature, pressure, and composition at the interface.

When to use Dynamic Surface Tension Measurement

Dynamic surface tension is essential for processes that involve rapid changes at the liquid-gas or liquid-liquid interface, such as droplet and bubble formation, coalescence (change in surface area), the behavior of foams, and the drying of paints (change in composition, e.g., evaporation of solvent). It is measured by analyzing the shape of a hanging droplet over time.

Dynamic surface tension applies to various industries, including cosmetics, coatings, pharmaceuticals, paint, food and beverage, and industrial processes, where understanding and controlling the behavior of liquid interfaces is essential for product quality and process efficiency.

Learn how Surface Tension measurement is done on our Tensiometer

For a more complete understanding of Surface Energy measurement, read our Surface Tension measurement: The Definitive Guide

Chapter 4: Surface Energy Measurement

Surface energy refers to the energy required to create a unit area of a new surface.
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Sample Image taken from Droplet Lab Tensiometer

Learn how Surface Energy measurement is done on our Tensiometer

For a more complete understanding of Surface Energy measurement, read our Surface Energy measurement: The Definitive Guide

For benchmark contact angle and surface energy values on glass, nylon, PMMA, and Teflon, see the Open Benchmark Data panel above or visit our Dataset Hub for full CSV downloads.

Chapter 5: Sliding Angle Measurement

The sliding angle measures the angle at which a liquid film slides over a solid surface. It is commonly employed to assess the slip resistance of a surface.

sliding angle 1

Sample Image taken from Droplet Lab Tensiometer

Learn how Sliding Angle measurement is done on our Tensiometer

For a more complete understanding of Sliding Angle measurement, read our Sliding Angle Measurement: The Definitive Guide

Chapter 6: Real-World Applications

Within the Transportation industry, several case studies exemplify the advantages of conducting surface property measurements.

Ice build up on aircraft wings

Coatings for wings and other exposed surfaces aim to slow ice formation and let ice release more easily. Water contact angle and sliding angle help rank candidate coatings on flat coupons. A low sliding angle means drops leave the surface before they can freeze in place.

ISO 19403-6 describes how to measure advancing and receding angles, and hysteresis, by changing drop volume. Hysteresis shows how strongly drops are pinned. Lab readings rank coatings; they do not replace icing wind tunnel or flight tests. Our sliding angle guide explains the method.

Ice build up on aircraft wings

Low wetting surfaces on titanium alloys

Titanium alloys are strong and light, but water and dirt that stay on the surface can still cause problems. Researchers make low wetting titanium surfaces by combining surface texture, such as anodizing or blasting, with a low energy surface chemistry. Contact angle and sliding angle show how well each process works.

Measure the bare alloy, then each treatment step, with the same drop volume and read time. For titanium parts that will later be bonded, the opposite goal applies, and a wetting check before bonding is the useful test. Our aluminum bonding page sets out that approach for light alloys.

Low wetting surfaces on titanium alloys

We are your partners in solving your Business & Technological challenges

If you are interested in implementing these or any other applications, please contact us.

Chapter 7: Standards and Guidelines

In an industry where precision reigns supreme, how can Transportation manufacturers ensure their products withstand scrutiny? The answer lies in standards and guidelines: the compass that guides them through the complex maze of quality and performance.

ISO 19403-6:2024, Dynamic Contact Angle (Advancing/Receding) by Drop-Volume Change

What it is

ISO 19403-6 specifies an optical sessile-drop method to measure dynamic advancing (θₐ) and dynamic receding (θᵣ) contact angles by increasing and decreasing droplet volume. It’s used to quantify wetting/dewetting behavior and contact-angle hysteresis (Δθ = θₐ − θᵣ) to help diagnose surface heterogeneity, contamination, or pretreatment drift on coated panels and substrates.

When to use it

Ready-to-coat / ready-to-bond verification:

Use dynamic θₐ/θᵣ (not just static angle) when you need early indication that surfaces will wet and resist dewetting before applying transportation coatings, adhesives, or sealants.

Root-cause triage & process drift monitoring

Use θₐ/θᵣ/Δθ trends and variability to separate likely chemistry/contamination drift from texture/heterogeneity/pinning effects when defects (e.g., fisheyes/craters, adhesion loss) start rising.

In-scope / Out-of-scope

In scope
  • Sessile-drop optical measurement with controlled volume increase/decrease (e.g., needle-in-drop dosing) to obtain dynamic angles.
  • Dynamic advancing (θₐ) during volume increase and dynamic receding (θᵣ) during volume decrease under a defined volume-change program.
  • Derived hysteresis (Δθ = θₐ − θᵣ) and spot-to-spot variability as diagnostic outputs for non-uniform surfaces.
  • Coated panels/substrates (common in transportation finishing and bonding workflows) using a documented SOP to lock controllables.
Out of scope
  • Universal pass/fail thresholds (limits must be calibrated to your downstream outcomes for each coating family + substrate + pretreatment).
  • Surface energy component analysis or direct liquid surface tension measurement (use other standards/methods for those).
  • Uncontrolled porous/absorbing surfaces where absorption dominates the droplet-volume/contact-line behavior without additional controls.
  • Alternative contact-angle methods (e.g., tilting plate, captive bubble, Wilhelmy) and replacing your instrument’s operating instructions.

Minimum you must report (checklist)

  • Standard + edition used (ISO 19403-6:2024) and your internal SOP ID (if applicable).
  • Substrate/coating description (material, finish) and pretreatment/treatment history, including time since treatment/cure.
  • Test liquid (identity, grade/concentration if relevant) and liquid temperature.
  • Drop/dosing geometry: sessile configuration, needle-in-drop (if used), needle type/size, and imaging/optics setup.
  • Volume-change program: start volume, step size or continuous rate, advance/recede rate, and dwell/settling rule.
  • Results: θₐ, θᵣ, and Δθ = θₐ − θᵣ, plus number of spots/replicates.
  • Statistics across spots: median + IQR (or mean + SD) and spot rejection/re-run criteria (edge fit QC, non-axisymmetric drops, vibration, unstable receding due to pinning).
  • Environment + controls: temperature/RH (if controlled) and reference (“golden”) panel or other run control results.

Dynamic contact angles are method-dependent, so your SOP must lock needle geometry, dosing rate, dwell, leveling, and fit/QC rules to keep trends comparable. If you see “ISO 19403-6:2023” internally, it commonly refers to a draft/DIS stage; the published ISO edition is 2024.

How to interpret results (guardrails)

  • θₐ increases vs baseline → poorer initial wetting; investigate treatment decay, low-energy residues, or contamination before coating/bonding.
  • θᵣ decreases or becomes unstable and/or Δθ increases → stronger pinning/dewetting tendency consistent with heterogeneity, roughness, contamination, or cure gradients; treat as a diagnostic signal, not a single-cause verdict.
  • High spot-to-spot variability (large IQR/SD) → non-uniform pretreatment/coating/additive distribution or localized contamination; use a panel map to locate outliers.
  • Always anchor interpretation to controls (golden panel stability) and calibrate Green/Yellow/Red limits to downstream metrics (adhesion, crater/fisheye rate, rework/scrap) for each process window.

Now It’s Your Turn

We hope this guide showed you how to apply surface science in the Transportation industry.

Now we’d like to turn it over to you: 

Feel free to leave a comment below—we’d love to hear from you.

Frequently asked questions

Which surface measurement should a transport engineering team start with?

Start with the failure you are trying to prevent. Use contact angle and sliding angle for repellent, anti icing and easy clean coatings. Use contact angle and surface free energy before painting or bonding. Use surface tension for battery electrolytes, paints and other process liquids. Our contact angle guide explains the core method.

Why measure sliding angle as well as contact angle?

A high contact angle shows that water is repelled. It does not show whether a drop will move. Some surfaces bead water at a high angle but pin the drop in place. Sliding angle on a tilt stage, together with contact angle hysteresis, shows whether drops roll off. See the roll off angle and hysteresis entries.

Which standards apply to wetting tests on transport coatings?

ISO 19403-6 describes dynamic contact angle by changing drop volume, which the Dropometer can run with its sessile drop modes. ISO 19403-7 describes roll off angle on a tilt stage; the Dropometer tilt stage reads up to 60 degrees. Neither standard sets pass limits, so build your own from parts with known field results.

Can lab tests predict how a rain repellent will perform on the road?

Lab tests rank coatings and catch drift between batches, but they do not replace road testing. They do not capture airflow at speed, wiper chatter or haze. Measure bare glass and a reference coating on the same day, then retest after wiper, washer fluid and UV cycles. Our windshield repellent page sets out the steps.

How do I check a metal surface before bonding?

Measure water contact angle at a fixed time after cleaning or treatment, at five or more spots per zone. Compare the median and the spread with parts that passed your lap shear or peel tests. There is no universal threshold, so gates are set per alloy and process. See reliable aluminum bonding.

Can the Dropometer measure battery electrolytes?

Yes. Pendant drop gives electrolyte surface tension, and sessile drop gives contact angle on separators and electrodes. Porous samples absorb drops fast, so absorption time can be the better measure. Moisture changes LiPF6 electrolytes, so control the air around the test. These readings rank materials; they do not replace cell builds. See electrolyte wetting.

How accurate is the Dropometer?

The drop shape method was validated against a KRUSS DSA100E in two peer reviewed papers, one in Review of Scientific Instruments and one in Colloids and Surfaces A. Published contact angle accuracy is 0.35 degrees. Automatic edge and baseline detection gives the same reading from the same image. See our validation papers.

Standards, evidence and resources

1. Use cases
  • Reliable aluminum bonding: Water contact angle on prepared aluminum panels and brackets, checked against joints that passed, catches poor surface preparation before bonding in rail and vehicle builds.
  • Windshield rain repellent performance: Static contact angle, sliding angle and hysteresis show whether a windshield rain repellent still clears water after wiper, washer fluid, UV and cold cycles.
  • Electrolyte and separator wetting: Pendant drop surface tension of electrolytes and contact angle on separators and electrodes help rank additives for lithium ion cells before long wetting and formation runs.
Case studies Example scenario: checking aluminum panels before bonding in rail car assembly. A rail car bonding team sets a water contact angle baseline on aluminum panels from joints that passed lap shear testing. Operators then read several spots on each panel after cleaning and hold any panel outside that baseline for cleaning again. The check catches poor surface preparation while the panel can still be reworked. Client citations (our analysis of each paper) Example scenario: ranking anti icing coatings for exposed transport surfaces. A university research group developing anti icing coatings for aircraft and rail surfaces measures water contact angle, hysteresis and sliding angle on flat coated coupons. The readings rank candidate coatings before the best few go to icing tests, and repeat readings after abrasion show which coatings keep their repellency. Use case collections Further resources