This is a complete guide to Surface Tension Measurement in (2024). In this all-new guide you will learn all about:
So, if you are looking to get an in-depth understanding of Surface Tension measurement, our guide is a valuable resource for you.
Surface tension measurement quantifies the elastic tendency of a liquid’s surface, representing the force per unit length exerted by the surface (interface); or put it another way, the energy required to generate a unit area of an interface. It results from an imbalance of cohesive forces molecules sitting at the interface of two bulk phases experience compared to molecules deep inside of each bulk phase. This measurement is critical for understanding how liquids interact with different materials, making it an essential parameter in various scientific and industrial applications.
Importance and applications in the industry
Surface tension measurement is vital for numerous applications across different industries:
Understanding surface tension enables the optimization of these processes, leading to improved product performance and innovation.
Surface tension results from an imbalance of cohesive forces molecules sitting at the interface of two bulk phases experience compared to molecules deep inside of each bulk phase.. In energetic terms, based on thermodynamic principles, it can be shown that the energy required to generate a unit area of an interface is equal to surface tension. As such there are two manifestations of surface tension, one based on mechanics, i.e. a force, and another based on energetics. Both are equally valid and depending on the system and process one or the other can be used.
Key aspects:
Surface tension influences various physical behaviors and industrial processes:
The ability to control and manipulate surface tension allows for the design of better products and more efficient industrial processes.
Surface and interfacial tensions are intimately related to contact angle measurement as they influence the wetting behavior of a liquid on a solid surface. For a given surface, high surface tension results in larger contact angles, as the liquid prefers not to wet the surface—while low surface tension leads to smaller contact angles, causing the liquid to spread. Understanding these tensions helps in predicting and controlling the wetting behavior of liquids on various surfaces.
For a more complete understanding of Contact Angle measurement, read our Contact Angle Measurement: The Definitive Guide.
Strictly speaking, these terms are equivalent, but in some contexts, surface tension refers to systems that involve liquid and air, whereas the interfacial tension term is used when one considers the interface of two immiscible fluids, such as oil and water, or a liquid and solid surface.
Surface tension varies depending on the conditions and the nature of the liquid interface. Below are the types/terminology of surface tension that are important to understand:
Static & Dynamic Surface Tension
Static Surface Tension refers to the surface tension measured at equilibrium, where the liquid interface has been undisturbed for a sufficient time to reach a stable state. This measurement is typically used to characterize liquids that are not in motion or subject to changes in composition or external forces.
Applications:
Dynamic Surface Tension describes the surface tension of a liquid under conditions where the surface is constantly changing, such as during rapid deformation, flow, or changes in concentration. This type is crucial for understanding the behavior of liquids in real-time processes where the interface is not static.
Applications:
Learn how Static and Dynamic Surface Tension measurement can be done using our Dropometer.
Interfacial Tension
Interfacial Tension is the force that acts at the interface between two immiscible liquids, such as oil and water. This tension is crucial for understanding emulsification, the stability of emulsions, and the separation processes in various industries.
Applications:
Equilibrium Surface Tension
Equilibrium Surface Tension is the surface tension measured after the system has reached a stable equilibrium, often used interchangeably with static surface tension. It assumes no further changes in the surface composition or structure.
Applications:
Critical Surface Tension is the surface tension at which a liquid just begins to wet a solid surface. It is a property of the solid surface and the liquid involved; it indicates the point at which complete wetting occurs. It is used to characterize the wettability of surfaces.
Applications:
Pure Liquid Surface Tension refers to the surface tension of a liquid in its pure state, without any additives or impurities. This type is critical for basic research and understanding fundamental fluid properties.
Applications:
Effective Surface Tension
Effective Surface Tension accounts for the presence of surfactants or impurities (particles) that can alter the surface properties of a liquid. It represents the surface tension in practical, real-world conditions.
Applications:
Relative Surface Tension compares the surface tension of different liquids or the same liquid under different conditions. It provides a comparative measure rather than an absolute one.
Applications:
High-Speed Surface Tension measures the surface tension of liquids under rapid deformation or high-speed processes. This is important for understanding the behavior of liquids in dynamic systems where traditional methods may not be sufficient.
Applications:
Nature of the Liquid: Different liquids have different inherent surface tensions due to their molecular structure and intermolecular forces. For example, water has a higher surface tension compared to organic solvents like ethanol.
Example: Water’s high surface tension is due to strong hydrogen bonding. Presence of Solutes: Adding solutes such as salts, acids, or bases can alter surface tension. Electrolytes typically increase surface tension, while non-electrolytes like alcohol decrease it.
Example: Sodium chloride increases the surface tension of water.
Direct Temperature Effects: Increasing the temperature decreases surface tension by reducing cohesive forces between molecules.
Example: Heating water reduces its surface tension as the kinetic energy of the molecules increases
Phase Change: The surface tension changes significantly at thermodynamic phase boundaries, such as from liquid to vapor.
Example: Surface tension drops sharply near the boiling point of a liquid.
Humidity: High humidity levels can reduce surface tension by adsorbing water molecules onto the surface, disrupting cohesive forces, and slowing evaporation rates.
Example: Surface tension of water decreases slightly in high humidity conditions due to the adsorption of water vapor.
Pressure: Changes in pressure can affect surface tension, especially in gasses.
Example: Increased pressure can slightly increase the surface 10 tension of gasses due to compression effects.
Surfactant Concentration: Adding surfactants lowers surface tension by accumulating at the liquid-air interface and disrupting cohesive forces.
Example: Soap or detergent in water significantly lowers its surface tension, facilitating wetting and spreading.
Nature and Behavior of Surfactants: Different surfactants have varying impacts depending on their concentration and molecular structure.
Example: Ionic surfactants may have a stronger effect on reducing surface tension than non-ionic ones at the same concentration.
Surface tension varies depending on the conditions and the nature of the liquid interface. Below are the types/terminology of surface tension that are important to understand:
Pendant Drop Method
The Pendant Drop Method involves suspending a droplet from the end of a tube or needle and capturing its shape with a camera. The shape of the droplet is analyzed to determine the surface tension.
Advantages:
Disadvantages:
Wilhelmy Plate Method
The Wilhelmy Plate Method measures the force exerted by the surface tension on a thin, vertically oriented plate that is partially submerged in the liquid.
Advantages:
Disadvantages:
Du Noüy Method
The Du Noüy Ring Method uses a ring, usually made of platinum-iridium, which is pulled vertically through the surface of the liquid to measure the force required to detach the ring from the surface.
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Disadvantages:
Rod Method
Advantages:
Disadvantages:
Bubble Pressure Method
Advantages:
Disadvantages:
Drop Volume Method
The Drop Volume Method measures the volume of a drop of liquid that detaches from a tube or needle, which can be used to determine surface tension.
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Disadvantages:
Surface Tension Measurements are utilized across various industries. Here are some examples of their applications in each field:
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Aviation & Space industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Biotech industry.
A chemical company faces the challenge of transitioning to sustainable methodologies amid growing environmental concerns, stringent regulations, and shifting customer preferences towards eco-friendly products. To tackle this challenge, the company leverages surface science as a transformative tool.
Contact angle and surface tension measurements play a crucial role in this transition by providing precise insights into the surface properties of materials. These measurements help the company evaluate and optimize the wetting characteristics and interactions of raw materials, leading to the development of more efficient catalysts. By understanding and manipulating these surface properties, researchers can enhance catalyst efficiency, reduce waste, and lower energy consumption, aligning with sustainable production principles.
As a result, the company significantly reduces its environmental impact, surpasses regulatory requirements, and positions itself as a leader in environmentally responsible chemical manufacturing. This shift not only benefits the environment but also leads to cost savings, market expansion, and a strengthened brand image, as consumers increasingly favor products that adhere to sustainability standards.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Chemicals industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Consumer Products industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Construction industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Electrical & Electronics industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Fabric industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Farming & Agriscience industry.
Imagine you’re a chocolatier, striving to create chocolates that not only taste exquisite but also have a captivating aesthetic. The technique of chocolate tempering is crucial for achieving the desired texture and glossy appearance. Traditionally, tempering requires precise temperature control, but surface science measurements simplify this process significantly.
By accurately measuring surface tension and surface energy, you can attain the optimal temper for chocolates. Manipulating these surface properties ensures your chocolates have a rich, pleasing texture and an appealing, shiny appearance that attracts consumers. Say goodbye to the inconsistencies of traditional tempering methods and embrace a more reliable and efficient approach that elevates the quality of your chocolate creations to new heights.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Food & Beverages industry.
Challenge: In 3D Printing, controlling the surface tension of printing materials is essential for achieving precise and high-quality prints.
Solution: Engineers have developed 3D printing material that has relatively low surface tension. Lower surface tension promotes better wetting and adhesion of the printing material to the build surface and between successive layers. Therefore, the new 3D printing material will offer improved print quality, reduced defects such as warping and delamination, and enhanced overall printing reliability. It will help the 3D printing material spread evenly across the build surface, creating strong bonds between layers and will reduce the likelihood of issues like “elephant’s foot” (excessive material squishing at the first layer) or “stringing” (unwanted thin strands of material).
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Mechanical / Industrial sector.
Challenge: Achieving efficient flotation in both copper and gold mining is crucial yet complex due to the need for selective attachment of valuable minerals to air bubbles while controlling wetting behavior and surface tension.
Solution: Flotation in mining relies heavily on the interaction between mineral particles and air bubbles. For copper mining, optimizing the contact angle is vital for selectively floating copper minerals and repelling gangue minerals like silica. Achieving an ideal contact angle of 00 ensures hydrophobicity, leading to a high-quality copper concentrate.
In gold mining, controlling surface tension is essential for creating a stable froth. This froth enables gold particles to attach to air bubbles and be separated effectively from gangue materials. Proper surface tension values ensure air bubbles have sufficient buoyancy and stability to carry gold particles to the surface, facilitating efficient recovery.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Mining & Metals industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Oil & Gas industry.
Challenge: The sterility of aseptic packages can be compromised during storage and distribution due to rough or improper handling.
Solution: In one study, scientists focused on determining the threshold pressure required to create a leak. They observed significantly lower threshold pressures in the case of low surface tension liquids, such as safranin red dye, compared to high surface tension liquids, like distilled water. This insight allows manufacturers to proactively avoid conditions that could lead to leakage issues. A tensiometer like Droplet Lab’s Dropometer precisely measures surface tension, enabling manufacturers to identify and understand how different liquids interact with packaging materials. By providing accurate data on surface tension, it helps in assessing the susceptibility of packaging to leaks and supports the development of more robust packaging solutions, thus maintaining package sterility.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Packaging & Containers industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Paint industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Pharmaceutical industry
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Semiconductors industry.
Challenge: A ship painting company faced uneven surface coatings due to the coating fluid’s viscosity, surface tension, and the substrate’s contact angle.
Solution: The company’s engineering team discovered that using a coating liquid with a contact angle less than 90° caused a pinning effect, reducing surface unevenness. By adjusting the contact angle to create this effect, they mitigated the impact of uneven coatings, leveraging the interplay between fluid viscosity and the substrate’s surface energy.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Shipbuilding industry.
Challenge: Water ingress into cables affects signal transmission.
Solution: Optimizing the surface tension values can prevent water ingress into cables. Lowering surface tension enhances the water-repellent properties of cable insulation. A telecommunications cable manufacturer develops cables with insulation materials specially designed with low surface tension. This kind of modification will improve water resistance which will reduce the risk of signal degradation in humid environments and ensure the long-term reliability of the communication infrastructure.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Telecom industry.
Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Utilities industry.
Measuring surface tension accurately presents several challenges due to the precision required and the sensitivity of the measurements to various factors. Below, we discuss key challenges in this process, including the importance of calibration, method-specific challenges, variability due to environmental conditions, and issues related to contamination and purity.
A. Importance of Calibration
Calibration is crucial to ensure that surface tension measurements are accurate and reliable. Proper calibration involves using reference materials with known surface tension values to adjust the measurement instrument.
B. Method-Specific Challenges
1. Pendant Drop Method
2. Wilhelmy Plate Method
3. Du Noüy Ring Method
4. Rod Method
5. Bubble Pressure Method
6. Drop Volume Method
C. Variability Due to Environmental Conditions
1. Temperature Fluctuations
2. Humidity
3. Air Currents
4. Vibrations
D. Contamination & Purity
1. Sample Purity
2. Equipment Contamination
3. Environmental Contaminants
Achieving reproducible surface tension measurements involves careful preparation, consistent procedures, and thorough calibration. Here is a detailed guide to ensure your measurements are accurate and reproducible.
A. Instrument Calibration
B. Environmental Control
C. Sample Preparation
A. Pendant Drop Method
B. Wilhelmy Plate Method
C. Du Noüy Ring Method
D. Rod Method
E. Bubble Pressure Method
F. Drop Volume Method
A. Consistent Procedures
B. Data Logging
C. Error Analysis
A. Routine Maintenance
B. Method Validation
Droplet Lab’s smartphone-based approach offers comparable surface tension measurement accuracy as traditional instruments, along with simplicity, compactness, and portability. This innovative method overcomes the challenges posed by smartphone optical zoom by utilizing an advanced image analysis algorithm.
Surface tension measurement using a smartphone is done by implementing the axisymmetric drop shape analysis (ADSA) method on the smartphone. The outline of the drop in an experiment was detected by the Otsu’s algorithm.Otsu’s algorithm can provide a better-quality of drop profile compared with other methods, e.g. Canny method. The YoungLaplace equation is solved by the Runge-Kutta method. In this instrument, the physical size of each image pixel is obtained by an automatic calibration system which measures the number of pixels in the capillary/ needle seen in the image (the needle diameter is needed as an 30 input).
Below is a Flow chart describing the principle of using axisymmetric drop shape analysis method to find the surface tension of liquids. And the Schematic of the experimental (yellow) and theoretical (green) drop profiles.
Experimental validation:
Error of the surface tension measurement instrument working with the synthetic drop profiles.
Comparison between surface tension measurements results from LG4 and traditional commercial instruments. The data of combined 32 measurement were obtained by using our program to measure the drop images obtained by the commercial instrument.
Comparison between surface tension measurements results from Nexus 5 and traditional commercial instruments. The data of combined measurement were obtained by using our program to measure the drop images obtained by the commercial instrument. For more detailed information please refer to the paper published by our founders in Colloids and Surfaces A.
Educational and practical applications:
A. Dynamic Surface Tension and Time-Dependent Phenomena
Dynamic surface tension refers to the variation of surface tension over time, especially when the surface is newly created or disturbed. This time-dependent behavior is critical in processes where surfaces are rapidly formed or altered, such as in coating applications, inkjet printing, and emulsification.
B. Marangoni Effect and Surface Tension Gradients
The Marangoni effect, also known as surface tension-driven flow, occurs when there are gradients in surface tension along a fluid interface. These gradients can result from variations in temperature, concentration, or the presence of surfactants.
C. Critical Micelle Concentration (CMC)
The Critical Micelle Concentration (CMC) is the concentration of surfactants in a solution at which micelles start to form. Beyond this concentration, additional surfactant molecules aggregate into micelles rather than adsorb to the interface.
Surface Tension measurements provide valuable insights into the materials, impacting fields such as materials science, chemistry, and manufacturing. By utilizing advanced technologies like high-resolution imaging and precise software analysis, these measurements can be conducted with greater accuracy and efficiency. Looking ahead, advancements in technology will lead to more precise measurements, aided by artificial intelligence. The future holds promise for eco-friendly materials and processes, driven by sustainable practices. From pharmaceuticals to consumer products, controlling surface tension will deliver innovative solutions for future challenges.
Droplet Lab was founded in 2016 by Dr. Alidad Amirfazli, faculty member at York University, and two of his researchers, Dr. Huanchen Chen and Dr. Jesus L. Muros-Cobos.
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