Surface Tension Measurement: The Definitive Guide (2024)

This is a complete guide to Surface Tension Measurement in (2024). In this all-new guide you will learn all about:

  • Basic Concepts & Principles
  • Measurement Techniques
  • The significance of Surface Tension measurement across various industries
  • Lots more

So, if you are looking to get an in-depth understanding of Surface Tension measurement, our guide is a valuable resource for you.

Introduction

Defining Surface Tension measurement

Surface tension measurement quantifies the elastic tendency of a liquid’s surface, representing the force per unit length exerted by the surface (interface); or put it another way, the energy required to generate a unit area of an interface. It results from an imbalance of cohesive forces molecules sitting at the interface of two bulk phases experience compared to molecules deep inside of each bulk phase. This measurement is critical for understanding how liquids interact with different materials, making it an essential parameter in various scientific and industrial applications.

Importance and applications in the industry

Surface tension measurement is vital for numerous applications across different industries:

  • Chemical and Pharmaceutical Industries: Helps in formulating stable emulsions, suspensions, and foams.
  • Coating and Printing: Essential for ensuring the proper spread and adhesion of inks and paints.
  • Consumer Products: Affects the quality and usability of products like detergents, cosmetics, and food.
  • Environmental Science: Crucial in studying pollutant behavior and the efficacy of oil spill treatments.

Understanding surface tension enables the optimization of these processes, leading to improved product performance and innovation.

Basic concepts and principles

What is surface tension?

Surface tension results from an imbalance of cohesive forces molecules sitting at the interface of two bulk phases experience compared to molecules deep inside of each bulk phase.. In energetic terms, based on thermodynamic principles, it can be shown that the energy required to generate a unit area of an interface is equal to surface tension. As such there are two manifestations of surface tension, one based on mechanics, i.e. a force, and another based on energetics. Both are equally valid and depending on the system and process one or the other can be used.

Key aspects:

  • Molecular Cohesion: Attraction between like molecules within the liquid.
Why surface tension is so important

Surface tension influences various physical behaviors and industrial processes:

  1. Fluid Dynamics: Affects the flow and stability of liquids in various systems, crucial in applications like inkjet printing and microfluidics.
  2. Interfacial Phenomena: Determines the interaction between different phases (e.g., liquid-liquid, liquid-gas), impacting emulsification, foaming, and wetting.
  3. Biological Systems: Plays a role in the function of biological membranes and the formation of cellular structures.
  4. Manufacturing and Material Science: Influences the properties of materials during processes like coating, painting, and fiber spinning.

The ability to control and manipulate surface tension allows for the design of better products and more efficient industrial processes.

Its role in contact angle measurement

Surface and interfacial tensions are intimately related to contact angle measurement as they influence the wetting behavior of a liquid on a solid surface. For a given surface, high surface tension results in larger contact angles, as the liquid prefers not to wet the surface—while low surface tension leads to smaller contact angles, causing the liquid to spread. Understanding these tensions helps in predicting and controlling the wetting behavior of liquids on various surfaces.

For a more complete understanding of Contact Angle measurement, read our Contact Angle Measurement: The Definitive Guide.

Surface tension versus interfacial tension?

Strictly speaking, these terms are equivalent, but in some contexts, surface tension refers to systems that involve liquid and air, whereas the interfacial tension term is used when one considers the interface of two immiscible fluids, such as oil and water, or a liquid and solid surface.

Surface Tension terminology in various applications

Surface tension varies depending on the conditions and the nature of the liquid interface. Below are the types/terminology of surface tension that are important to understand:

Static & Dynamic Surface Tension

Static Surface Tension refers to the surface tension measured at equilibrium, where the liquid interface has been undisturbed for a sufficient time to reach a stable state. This measurement is typically used to characterize liquids that are not in motion or subject to changes in composition or external forces.

Applications:

  • Used in the formulation of detergents and surfactants.
  • Relevant in processes like coating and painting, where a stable interface is crucial.

Dynamic Surface Tension describes the surface tension of a liquid under conditions where the surface is constantly changing, such as during rapid deformation, flow, or changes in concentration. This type is crucial for understanding the behavior of liquids in real-time processes where the interface is not static.

Applications:

  • Important in processes involving rapid mixing or spreading, such as inkjet printing.
  • Relevant in the pharmaceutical industry for drug delivery systems involving emulsions.

Learn how Static and Dynamic Surface Tension measurement can be done using our Dropometer.

Interfacial Tension

Interfacial Tension is the force that acts at the interface between two immiscible liquids, such as oil and water. This tension is crucial for understanding emulsification, the stability of emulsions, and the separation processes in various industries.

Applications:

  • Key in oil recovery processes and the formulation of emulsions.
  • Used in the food industry to stabilize mixtures of oil and water.

Equilibrium Surface Tension

Equilibrium Surface Tension is the surface tension measured after the system has reached a stable equilibrium, often used interchangeably with static surface tension. It assumes no further changes in the surface composition or structure.

Applications:

  • Used in quality control of products where a stable surface is critical, such as coatings and adhesives.
  • Relevant in environmental studies for understanding the behavior of pollutants
Critical Surface Tension

Critical Surface Tension is the surface tension at which a liquid just begins to wet a solid surface. It is a property of the solid surface and the liquid involved; it indicates the point at which complete wetting occurs. It is used to characterize the wettability of surfaces.

Applications:

  • Important in selecting materials for coatings and adhesives to ensure optimal wetting. 
  • Used in designing surfaces for specific interactions with liquids, such as in biomedical devices.
Pure Liquid Surface Tension

Pure Liquid Surface Tension refers to the surface tension of a liquid in its pure state, without any additives or impurities. This type is critical for basic research and understanding fundamental fluid properties.

Applications:

  • Used as a reference in scientific research and material science.
  • Relevant in the development of new fluids and materials.

Effective Surface Tension

Effective Surface Tension accounts for the presence of surfactants or impurities (particles) that can alter the surface properties of a liquid. It represents the surface tension in practical, real-world conditions.

Applications:

  • Crucial in industrial processes where surfactants are used to modify surface properties, such as in cleaning agents and lubricants.
  • Relevant in biological systems where natural surfactants influence surface behavior.
Relative Surface Tension

Relative Surface Tension compares the surface tension of different liquids or the same liquid under different conditions. It provides a comparative measure rather than an absolute one. 

Applications:

  • Used in selecting fluids for specific applications where relative properties are more important than absolute values.
  • Relevant in formulating mixtures where the balance of surface tensions affects performance.
High-Speed Surface Tension

High-Speed Surface Tension measures the surface tension of liquids under rapid deformation or high-speed processes. This is important for understanding the behavior of liquids in dynamic systems where traditional methods may not be sufficient.

Applications:

  • Crucial in high-speed manufacturing processes like spin coating or high-speed printing.
  • Used in studying the breakup and formation of droplets in high-speed flows

What factors affect the Surface Tension?

Chemical Composition

Nature of the Liquid: Different liquids have different inherent surface tensions due to their molecular structure and intermolecular forces. For example, water has a higher surface tension compared to organic solvents like ethanol.


Example: Water’s high surface tension is due to strong hydrogen bonding. Presence of Solutes: Adding solutes such as salts, acids, or bases can alter surface tension. Electrolytes typically increase surface tension, while non-electrolytes like alcohol decrease it.

Example: Sodium chloride increases the surface tension of water.

Temperature

Direct Temperature Effects: Increasing the temperature decreases surface tension by reducing cohesive forces between molecules.

Example: Heating water reduces its surface tension as the kinetic energy of the molecules increases

Phase Change: The surface tension changes significantly at thermodynamic phase boundaries, such as from liquid to vapor.

Example: Surface tension drops sharply near the boiling point of a liquid.

Environmental Factors

Humidity: High humidity levels can reduce surface tension by adsorbing water molecules onto the surface, disrupting cohesive forces, and slowing evaporation rates.

Example: Surface tension of water decreases slightly in high humidity conditions due to the adsorption of water vapor.

Pressure: Changes in pressure can affect surface tension, especially in gasses.

Example: Increased pressure can slightly increase the surface 10 tension of gasses due to compression effects.

Surface-Active Agents (Surfactants)

Surfactant Concentration: Adding surfactants lowers surface tension by accumulating at the liquid-air interface and disrupting cohesive forces.

Example: Soap or detergent in water significantly lowers its surface tension, facilitating wetting and spreading.

Nature and Behavior of Surfactants: Different surfactants have varying impacts depending on their concentration and molecular structure.

Example: Ionic surfactants may have a stronger effect on reducing surface tension than non-ionic ones at the same concentration.

Measurement Techniques

Surface tension varies depending on the conditions and the nature of the liquid interface. Below are the types/terminology of surface tension that are important to understand:

Pendant Drop Method

The Pendant Drop Method involves suspending a droplet from the end of a tube or needle and capturing its shape with a camera. The shape of the droplet is analyzed to determine the surface tension.

Advantages:

  • Suitable for measuring small sample volumes.
  • Can be used for both liquids and liquid-liquid interfaces.
  • Provides accurate measurements with minimal sample disturbance.
  • Provides surface area information together with surface tension
  • Can make dynamic as well as static measurements 
  • Non-contact

Disadvantages:

  • Requires precise control and imaging equipment.
  • Not suitable for highly volatile liquids.

Wilhelmy Plate Method

The Wilhelmy Plate Method measures the force exerted by the surface tension on a thin, vertically oriented plate that is partially submerged in the liquid.

Advantages:

  • Simple and direct method.
  • Can be used for a wide range of liquids.
  • Provides accurate and repeatable results.

Disadvantages:

  • Requires careful cleaning of the plate to avoid contamination.
  • Not suitable for highly viscous or gel-like liquids.
  • The method is sensitive to surface impurities due to large amounts of liquid surface

Du Noüy Method

The Du Noüy Ring Method uses a ring, usually made of platinum-iridium, which is pulled vertically through the surface of the liquid to measure the force required to detach the ring from the surface.

Advantages:

  • Suitable for a variety of liquids, including those with low surface tension.
  • Provides consistent measurements if the ring is properly maintained.
  • Can measure both surface and interfacial tension.

Disadvantages:

  • Requires calibration and careful handling of the ring.
  • Results can be affected by contamination or roughness on the ring surface.
  • The method is less accurate for highly viscous or elastic liquids.

Rod Method

The Rod Method involves immersing a rod into the liquid and measuring the force required to withdraw the rod from the surface

Advantages:

  • Simple and cost-effective method.
  • Suitable for preliminary measurements and educational purposes.
  • Can be used with various rod materials.

Disadvantages:

  • Less accurate compared to other methods like the Wilhelmy Plate.
  • Affected by the rod’s surface condition and cleanliness.
  • Not suitable for very low surface tension liquids.

Bubble Pressure Method

The Bubble Pressure Method measures the pressure required to form a bubble at the tip of a submerged tube or needle, providing information about dynamic surface tension.

Advantages:

  • Suitable for studying dynamic surface tension in real-time.
  • Useful for surfactant solutions and rapid interface changes.
  • Can be automated for continuous monitoring.

Disadvantages:

  • Requires precise pressure control and measurement.
  • Not suitable for static surface tension measurements.
  • Limited to liquids that can form stable bubbles.

Drop Volume Method

The Drop Volume Method measures the volume of a drop of liquid that detaches from a tube or needle, which can be used to determine surface tension.

Advantages:

  • Simple and inexpensive method.
  • Suitable for small sample volumes.
  • Can be used for both liquid and liquid-liquid interfaces.

Disadvantages:

  • Less accurate than other methods like the Pendant Drop.
  • Affected by drop formation dynamics and evaporation.
  • Not suitable for highly volatile or viscous liquids

Comparison of Techniques

Accuracy and Precision
  • Pendant Drop and Wilhelmy Plate: High accuracy and precision; suitable for detailed studies.
  • Du Noüy Ring: Reliable for a variety of liquids but sensitive to contamination.
  • Rod Method and Drop Volume: Suitable for educational and preliminary measurements; lower precision.
Suitability for Different Liquids
  • Bubble Pressure and Drop Volume: Better for dynamic and small volume samples.
  • Pendant Drop and Du Noüy Ring: Suitable for a wide range of liquid viscosities and
    surface tensions.
  • Wilhelmy Plate: Best for liquids with consistent surface properties.
Ease of Use
  • Rod Method and Drop Volume: Simple and easy to implement; suitable for beginners.
  • Pendant Drop and Wilhelmy Plate: In automated versions very easy to work with and
    suitable for both research and development work, as well as quality control.
Cost and Equipment
  • Rod Method and Drop Volume: Low-cost and minimal equipment.
  • Pendant Drop and Wilhelmy Plate: Higher cost due to imaging and force measurement
    equipment.

Applications of Surface Tension Measurement

Surface Tension Measurements are utilized across various industries. Here are some examples of their applications in each field:

I. Automotive Industry
II. Aviation & Space

The Role of Paint in Aircraft Maintenance

Think about it: Airplane paint isn’t just for looks. Weighing in at a hefty 500 kg, it significantly impacts the aircraft’s fuel consumption. But it goes beyond weight management. Paint acts as the aircraft’s first line of defense against often-overlooked enemies like corrosive rain and harsh UV radiation. Therefore, aircraft paint needs to meet several crucial demands: high surface energy, excellent wettability, and minimal weight. At Droplet Lab, our tensiometer helps strike this delicate balance, resulting in aircraft paints that are both durable and fuel-efficient.
The Role of Paint in Aircraft Maintenance

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Aviation & Space industry.

III. Biotechnology

Creating Life with Surface Coatings

Medical implants, scaffolds, and biosensors are transforming our lives and becoming everyday reality. Understanding how different biomaterial surfaces interact with water, either attracting (hydrophilic) or repelling (hydrophobic) it, is crucial. This knowledge directly impacts everything from cell adhesion to tissue regeneration. For example, by carefully adjusting the surface energy and roughness of a substrate, we can significantly enhance cell growth. Surface tension plays a key role in fabricating hybrid materials. We can combine 3D printed polymers with cell-laden hydrogels to create fully biocompatible, 3D structures of living tissues. This innovative approach utilizes surface-wetting forces to suspend liquid films across the openings of a mesh, which can then be converted into a solid coating or hydrogel.
Creating Life with Surface Coatings

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Biotech industry.

IV. Chemicals

Sustainable Chemical Production

A chemical company faces the challenge of transitioning to sustainable methodologies amid growing environmental concerns, stringent regulations, and shifting customer preferences towards eco-friendly products. To tackle this challenge, the company leverages surface science as a transformative tool.

Contact angle and surface tension measurements play a crucial role in this transition by providing precise insights into the surface properties of materials. These measurements help the company evaluate and optimize the wetting characteristics and interactions of raw materials, leading to the development of more efficient catalysts. By understanding and manipulating these surface properties, researchers can enhance catalyst efficiency, reduce waste, and lower energy consumption, aligning with sustainable production principles.

As a result, the company significantly reduces its environmental impact, surpasses regulatory requirements, and positions itself as a leader in environmentally responsible chemical manufacturing. This shift not only benefits the environment but also leads to cost savings, market expansion, and a strengthened brand image, as consumers increasingly favor products that adhere to sustainability standards.

Sustainable Chemical Production

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Chemicals industry.

V. Consumer Products

The polydimethylsiloxane (PDMS) Wetting by Water

PDMS, despite being hydrophobic, surprisingly absorbs up to ~30 mM of water upon contact. Researchers addressed this challenge by measuring advancing and receding contact angles of water droplets on cross-linked PDMS. They discovered that PDMS adapts to water by enriching the interface with free oligomers, leading to a net decrease in surface tension. This crucial information helps us develop strategies to minimize water affinity and improve the performance of PDMS materials.
The polydimethylsiloxane (PDMS) Wetting by Water

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Consumer Products industry.

VI. Construction

Water Leakage in Underground Parking Structures

Challenge: Water leakage in an underground parking structure was causing vehicle damage and structural deterioration. Solution: A waterproofing membrane with low surface tension was applied to the concrete surfaces. This membrane provided effective water repellency, preventing water infiltration and preserving the integrity of the parking structure while protecting the vehicles.
Water Leakage in Underground Parking Structures

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Construction industry.

VII. Cosmetics
VIII. Electrical & Electronics

Managing Liquid Metal Shape for Stretchable Electronics

Scenario: Liquid metals (LMs) are conducting like other metals, at the same time, they also possess the stretchable behaviour of liquid at room temperature. This property makes them suitable for stretchable electronics. Application: An electronics manufacturer faces the big problem of attaining the desired shape as due to high surface tension LM’s tend to form spherical shapes. To deal with this issue the manufacturer decided to break up the material into smaller chunks. They then decided to stabilize the smaller chunks using a suitable surfactant. This helped them to achieve the desired values of surface tension and hence the desired shape of the LMs.
Managing Liquid Metal Shape for Stretchable Electronics

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Electrical & Electronics industry.

IX. Fabrics Industry

Revolutionizing Inkjet Textile Printing

In the captivating world of printing intricate designs on textiles with inkjet technology, experts meticulously tweak the fabric’s surface properties to ensure the perfect canvas. Textile and printing companies analyze surface tension and contact angles, not passively observing, but actively manipulating them to guarantee the fabric flawlessly holds the ink. This meticulous attention to detail prevents smudging and blurring, resulting in sharp, vibrant, and eye-catching patterns that come alive on the fabric.
Revolutionizing Inkjet Textile Printing

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Fabric industry.

X. Farming & Agriscience

Pesticide Adhesion

Challenge: Uneven pesticide distribution can lead to pest infestations and diseases in agriculture. Importance of Contact Angle: Proper contact angles in pesticide formulations ensure balanced coverage on plant surfaces. Solution: A farm tested various pesticide formulations with different contact angles. They found that formulations with a contact angle close to zero adhered better to plant leaves, reducing pesticide runoff and enhancing pest control, which led to healthier crops.
Pesticide Adhesion

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Farming & Agriscience industry.

XI. Food & Beverages

Perfecting Chocolate Tempering

Imagine you’re a chocolatier, striving to create chocolates that not only taste exquisite but also have a captivating aesthetic. The technique of chocolate tempering is crucial for achieving the desired texture and glossy appearance. Traditionally, tempering requires precise temperature control, but surface science measurements simplify this process significantly.

By accurately measuring surface tension and surface energy, you can attain the optimal temper for chocolates. Manipulating these surface properties ensures your chocolates have a rich, pleasing texture and an appealing, shiny appearance that attracts consumers. Say goodbye to the inconsistencies of traditional tempering methods and embrace a more reliable and efficient approach that elevates the quality of your chocolate creations to new heights.

Perfecting Chocolate Tempering

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Food & Beverages industry.

XII. Mechanical / Industrial

Enhanced 3D Printing

Challenge: In 3D Printing, controlling the surface tension of printing materials is essential for achieving precise and high-quality prints.

Solution: Engineers have developed 3D printing material that has relatively low surface tension. Lower surface tension promotes better wetting and adhesion of the printing material to the build surface and between successive layers. Therefore, the new 3D printing material will offer improved print quality, reduced defects such as warping and delamination, and enhanced overall printing reliability. It will help the 3D printing material spread evenly across the build surface, creating strong bonds between layers and will reduce the likelihood of issues like “elephant’s foot” (excessive material squishing at the first layer) or “stringing” (unwanted thin strands of material).

Enhanced 3D Printing

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Mechanical / Industrial sector.

XIII. Medical Device Industry
XIV. Mining & Metals

Innovative Flotation Techniques in Mining

Challenge: Achieving efficient flotation in both copper and gold mining is crucial yet complex due to the need for selective attachment of valuable minerals to air bubbles while controlling wetting behavior and surface tension.

Solution: Flotation in mining relies heavily on the interaction between mineral particles and air bubbles. For copper mining, optimizing the contact angle is vital for selectively floating copper minerals and repelling gangue minerals like silica. Achieving an ideal contact angle of 0 ensures hydrophobicity, leading to a high-quality copper concentrate.

In gold mining, controlling surface tension is essential for creating a stable froth. This froth enables gold particles to attach to air bubbles and be separated effectively from gangue materials. Proper surface tension values ensure air bubbles have sufficient buoyancy and stability to carry gold particles to the surface, facilitating efficient recovery.

Innovative Flotation Techniques in Mining

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Mining & Metals industry.

XV. Oil & Gas

Enhanced Oil Recovery

In enhanced oil recovery techniques like surfactant flooding, engineers actively utilize surface property measurements to optimize the process. They reduce surface tension between oil and water using surfactants, allowing for easier oil recovery. These measurements help them determine the ideal surfactant concentration and continuously monitor the effectiveness of the surfactant flooding process.
Enhanced Oil Recovery

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Oil & Gas industry.

XVI. Packaging & Containers

Loss of Package Sterility due to Leaker Formation

Challenge: The sterility of aseptic packages can be compromised during storage and distribution due to rough or improper handling.

Solution: In one study, scientists focused on determining the threshold pressure required to create a leak. They observed significantly lower threshold pressures in the case of low surface tension liquids, such as safranin red dye, compared to high surface tension liquids, like distilled water. This insight allows manufacturers to proactively avoid conditions that could lead to leakage issues. A tensiometer like Droplet Lab’s Dropometer precisely measures surface tension, enabling manufacturers to identify and understand how different liquids interact with packaging materials. By providing accurate data on surface tension, it helps in assessing the susceptibility of packaging to leaks and supports the development of more robust packaging solutions, thus maintaining package sterility.

Loss of Package Sterility due to Leaker Formation

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Packaging & Containers industry.

XVII. Paint

Glass Goals: Fogging No More

A paint manufacturer yearns for the perfect glass paint, one that stands strong against the bane of fogging and streaking. Driven by this vision, they embark on a quest to unravel the secrets of surface properties. The shocking truth? The paint’s high surface tension was the culprit. With a spark of innovation, they skillfully modify the formula, significantly lowering its surface tension. The result? Pure magic – paint that glides effortlessly on glass, leaving no trace of fog or streaks behind.
Glass Goals: Fogging No More

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Paint industry.

XVIII. Pharmaceutical

Optimizing Inhalable Medications

Consider a pharmaceutical company developing inhalable medications for respiratory conditions. The effectiveness of these medications relies on producing aerosol droplets of a precise size to effectively reach the lungs. By measuring the surface tension of the liquid formulation used in the aerosol, the company can optimize the spray characteristics to achieve the desired droplet size and uniformity. This process ensures the medication is delivered directly to the target site within the lungs, maximizing its therapeutic effect.
Optimizing Inhalable Medications

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Pharmaceutical industry

XIX. Plastics
XX. Semiconductors

Managing Receding Meniscus in Immersion Lithography

To achieve successful immersion lithography, meticulous management of the immersion fluid is crucial. A major failure point is the receding meniscus event, which leaves residual liquid behind on the wafer as a thin film or droplets. Ideally, the immersion fluid should be confined near the lens, allowing the wafer to scan smoothly during exposure. For a semiconductor manufacturer, the meniscus failure mechanism remained a significant hurdle, hindering the successful implementation of immersion lithography. Recognizing the critical role of surface forces in drainage and pattern collapse during lithography, they sought a solution from a laboratory. The scientists, understanding the importance, developed a new fluid formulation with precisely tailored surface tension characteristics that facilitated proper liquid drainage, eliminating the meniscus issue.
Managing Receding Meniscus in Immersion Lithography

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Semiconductors industry.

XXI. Shipbuilding

Unevenness in Surface Coating

Challenge: A ship painting company faced uneven surface coatings due to the coating fluid’s viscosity, surface tension, and the substrate’s contact angle.

Solution: The company’s engineering team discovered that using a coating liquid with a contact angle less than 90° caused a pinning effect, reducing surface unevenness. By adjusting the contact angle to create this effect, they mitigated the impact of uneven coatings, leveraging the interplay between fluid viscosity and the substrate’s surface energy.

Unevenness in Surface Coating

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Shipbuilding industry.

XXII. Telecom

Improving Cable Insulation in Humid Environments

Challenge: Water ingress into cables affects signal transmission.

Solution: Optimizing the surface tension values can prevent water ingress into cables. Lowering surface tension enhances the water-repellent properties of cable insulation. A telecommunications cable manufacturer develops cables with insulation materials specially designed with low surface tension. This kind of modification will improve water resistance which will reduce the risk of signal degradation in humid environments and ensure the long-term reliability of the communication infrastructure.

Improving Cable Insulation in Humid Environments

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Telecom industry.

XXIII. Transportation
XXIV. Utilities

Transformers insulation failure from aging

Aging transformers face the challenge of insulation failure, which can have severe consequences for both safety and economic impact if not identified and addressed quickly. Scheduled maintenance practices employ various laboratory techniques as solutions for aging detection. These methods include breakdown voltage (BDV), spectroscopy, dissolved gas analysis, total acid number, and interfacial tension. A previous study suggests that interfacial tension (IFT) and total acid number (TAN) are more accurate reflections of transformer oil aging compared to other techniques, which can be influenced by unrelated parameters. Since assessing interfacial tension involves evaluating the oil’s surface tension, evaluating surface properties becomes crucial in studying aging-related insulation failure in transformers.
Transformers insulation failure from aging

Explore other applications of Surface Tension measurement and lots more in our Practical Guide to Surface Science for the Utilities industry.

Challenges in Surface Tension Measurement

Measuring surface tension accurately presents several challenges due to the precision required and the sensitivity of the measurements to various factors. Below, we discuss key challenges in this process, including the importance of calibration, method-specific challenges, variability due to environmental conditions, and issues related to contamination and purity.

A. Importance of Calibration

Calibration is crucial to ensure that surface tension measurements are accurate and reliable. Proper calibration involves using reference materials with known surface tension values to adjust the measurement instrument.

  • Reference Standards: Use standards like pure water or n-decane with well-known surface tension properties for calibration.
  • Regular Calibration: Instruments should be calibrated regularly, especially before measurements involving different liquids or environmental conditions.
  • Temperature Control: Since surface tension is temperature-dependent, calibration should account for and control temperature variations.

B. Method-Specific Challenges

1. Pendant Drop Method

  • Image Quality: Clear imaging is required to capture the drop shape accurately, and poor image quality can lead to incorrect measurements.
  • Drop Stability: Ensuring the droplet remains stable and free from vibrations or air currents is essential for accurate measurement.

2. Wilhelmy Plate Method

  • Plate Cleanliness: Any contamination or surface irregularities on the plate can affect the force measurement.
  • Contact Angle Variability: The method assumes a contact angle of 0°, and deviations can introduce errors.

3. Du Noüy Ring Method

  • Ring Geometry: Any deformation or contamination of the ring can alter the measured force, leading to errors.
  • Contact Angle Variability: The method assumes a contact angle of 0°, and deviations can introduce errors.
  • Meniscus Formation: Accurate measurement requires proper meniscus formation around the ring, which can be affected by the liquid’s properties.

4. Rod Method

  • Surface Condition: The condition of the rod’s surface must be uniform and clean to avoid inconsistent force measurements.
  • Liquid Withdrawal Rate: The rate at which the rod is withdrawn from the liquid can impact the measured force and thus the calculated surface tension.

5. Bubble Pressure Method

  • Pressure Control: Precise control of the pressure is needed to maintain a constant bubble size, which is critical for accurate measurements.
  • Bubble Formation: Inconsistent bubble formation can lead to variability in the measured dynamic surface tension.

6. Drop Volume Method

  • Drop Size Consistency: Consistent drop size is essential for accurate volume measurements, and variations can lead to errors.
  • Evaporation: Evaporation of the liquid during measurement can affect the drop volume and lead to inaccuracies.

C. Variability Due to Environmental Conditions

1. Temperature Fluctuations

  • Impact on Surface Tension: Surface tension decreases with increasing temperature. Temperature fluctuations can thus lead to variability in measurements.
  • Temperature Control: Instruments and samples should be maintained at a constant temperature to ensure reliable results.

2. Humidity

  • Humidity Effects: High humidity can lead to condensation or absorption of moisture, particularly affecting hydrophilic surfaces or hygroscopic liquids.
  • Control Measures: Measurements should be conducted in a controlled environment with stable humidity levels to minimize its impact.

3. Air Currents

  • Influence on Measurements: Air currents can disturb the liquid surface or droplet shape, introducing variability.
  • Shielding: Shielding the measurement setup from air currents can help maintain consistency.

4. Vibrations

  • Disturbances: Vibrations can disrupt the equilibrium of the liquid surface or the stability of droplets, affecting the measurements.
  • Isolation: Using vibration isolation techniques or conducting measurements in a vibration-free environment can mitigate this issue.

D. Contamination & Purity

1. Sample Purity

  • Effect of Impurities: Impurities in the liquid can significantly alter its surface tension. Even small amounts of contaminants can lead to erroneous measurements.
  • Sample Preparation: Samples should be prepared and handled in a clean environment to prevent contamination.

2. Equipment Contamination

  • Residuals on Equipment: Residual contaminants on measurement equipment, like plates, rings, or needles, can affect the surface tension of the liquid being measured.
  • Cleaning Protocols: Implementing rigorous cleaning protocols for all measurement equipment is crucial for obtaining accurate results.

3. Environmental Contaminants

  • Airborne Particles: Dust or other airborne particles can settle on the liquid surface, altering its properties and affecting measurements.
  • Clean Environment: Performing measurements in a clean, controlled environment helps reduce the impact of airborne contaminants.

How to perform Reproducible Surface Tension Measurement

Achieving reproducible surface tension measurements involves careful preparation, consistent procedures, and thorough calibration. Here is a detailed guide to ensure your measurements are accurate and reproducible.

A. Instrument Calibration

  • Use Standard Reference Liquids: Calibrate your instrument using liquids with well-documented surface tensions (e.g., pure water and dodecane).
  • Regular Calibration Checks: Calibrate before each measurement session and periodically during extended sessions.

B. Environmental Control

  • Stable Temperature: Conduct measurements in a temperature-controlled environment (if possible) to prevent fluctuations.
  • Humidity Control: Maintain consistent humidity levels, as high humidity can affect the liquid’s properties.
  • Minimize Air Currents: Perform measurements in a draft-free area to avoid disturbances to the liquid surface or droplet.

C. Sample Preparation

  • Use High-Purity Liquids: Ensure the liquid used is free from contaminants and has a known composition (unless the purpose of the measurement is to understand the effects on surface tension by surfactant, etc.)
  • Consistent Handling: Prepare and handle samples in a clean environment to avoid introducing impurities.

A. Pendant Drop Method

  • Setup: Position a drop of liquid suspended from a needle.
  • Image Capture: Use high-resolution imaging to capture the shape of the drop.
  • Analysis: Analyze the drop shape to determine the surface tension using software that fits the Young-Laplace equation.
  • Consistency: Ensure consistent drop size and formation time.
  • A well deformed droplet should be used for the best results.

B. Wilhelmy Plate Method

  • Setup: Submerge a clean, vertically positioned plate into the liquid.
  • Measurement: Measure the force exerted on the plate due to surface tension.
  • Consistency: Ensure the plate is consistently clean and properly oriented each time.

C. Du Noüy Ring Method

  • Setup: Submerge a platinum-iridium ring into the liquid.
  • Measurement: Slowly pull the ring through the liquid surface and measure the force required to detach it.
  • Consistency: Maintain a constant ring geometry and clean the ring thoroughly before each measurement.

D. Rod Method

  • Setup: Insert a thin rod into the liquid.
  • Measurement: Measure the force on the rod as it is pulled through the liquid surface.
  • Consistency: Ensure the rod’s surface is uniformly clean and smooth.

E. Bubble Pressure Method

  • Setup: Generate bubbles in the liquid at a controlled rate.
  • Measurement: Measure the pressure required to form bubbles at the liquid interface.
  • Consistency: Maintain a stable bubble formation rate and use clean apparatus to prevent bubble size variability.

F. Drop Volume Method

  • Setup: Form a drop at the tip of a nozzle.
  • Measurement: Measure the volume of liquid in the drop just before it detaches.
  • Consistency: Ensure a uniform drop formation rate and nozzle cleanliness.

A. Consistent Procedures

  • Follow Protocols: Adhere strictly to established protocols for each measurement technique.
  • Repeat Measurements: Perform multiple measurements and use statistical methods to analyze variability and ensure reproducibility.

B. Data Logging

  • Measurement Conditions: Record all relevant conditions (temperature, humidity, instrument settings) during each measurement session.
  • Automated Data Capture: Use software tools to capture and analyze data automatically, reducing human error.

C. Error Analysis

  • Identify Outliers: Analyze the data to identify and understand any outliers or inconsistencies.
  • Assess Repeatability: Calculate standard deviations and coefficients of variation to assess the repeatability of measurements.

A. Routine Maintenance

  • Clean Instruments: Regularly clean all instruments and components that come into contact with the liquid.
  • Check for Wear: Inspect instruments for signs of wear or damage that could affect measurements.

B. Method Validation

  • Inter-laboratory Comparisons: Compare results with other laboratories to validate methods and ensure consistency (if possible or necessary).
  • Reference Materials: Use reference materials periodically to validate the accuracy of your measurements.

How Droplet Lab Measures Surface Tension Using a Smartphone

Droplet Lab’s smartphone-based approach offers comparable surface tension measurement accuracy as traditional instruments, along with simplicity, compactness, and portability. This innovative method overcomes the challenges posed by smartphone optical zoom by utilizing an advanced image analysis algorithm.

Surface tension measurement using a smartphone is done by implementing the axisymmetric drop shape analysis (ADSA) method on the smartphone. The outline of the drop in an experiment was detected by the Otsu’s algorithm.Otsu’s algorithm can provide a better-quality of drop profile compared with other methods, e.g. Canny method. The YoungLaplace equation is solved by the Runge-Kutta method. In this instrument, the physical size of each image pixel is obtained by an automatic calibration system which measures the number of pixels in the capillary/ needle seen in the image (the needle diameter is needed as an 30 input).

Below is a Flow chart describing the principle of using axisymmetric drop shape analysis method to find the surface tension of liquids. And the Schematic of the experimental (yellow) and theoretical (green) drop profiles.

Experimental validation:

  • The smartphone instrument’s performance was tested against synthetic drops with known surface tension, achieving an accuracy of 0.001%.

Error of the surface tension measurement instrument working with the synthetic drop profiles.

Practical measurements compared with high-end commercial instruments showed remarkable consistency and precision.

Comparison between surface tension measurements results from LG4 and traditional commercial instruments. The data of combined 32 measurement were obtained by using our program to measure the drop images obtained by the commercial instrument.

Comparison between surface tension measurements results from Nexus 5 and traditional commercial instruments. The data of combined measurement were obtained by using our program to measure the drop images obtained by the commercial instrument. For more detailed information please refer to the paper published by our founders in Colloids and Surfaces A.

Educational and practical applications:

  • Affordable and accessible for educational purposes, the smartphone
    method allows students to learn about surface tension measurement
    without expensive equipment.
  • Practical for in situ or fieldwork, it provides accurate measurements
    comparable to traditional lab-based instruments.

Advanced Topics

A. Dynamic Surface Tension and Time-Dependent Phenomena

Dynamic surface tension refers to the variation of surface tension over time, especially when the surface is newly created or disturbed. This time-dependent behavior is critical in processes where surfaces are rapidly formed or altered, such as in coating applications, inkjet printing, and emulsification.

  • New Surface Formation: When a new surface is created, the surface tension is not instantaneously at equilibrium. It evolves as molecules at the interface rearrange or adsorb from the bulk phase.
  • Adsorption Dynamics: The rate at which surfactants or other surface-active agents adsorb to the interface can significantly impact dynamic surface tension. Surfactant adsorption can lower surface tension over time until equilibrium is reached.

B. Marangoni Effect and Surface Tension Gradients

The Marangoni effect, also known as surface tension-driven flow, occurs when there are gradients in surface tension along a fluid interface. These gradients can result from variations in temperature, concentration, or the presence of surfactants.

  • Thermal Marangoni Effect: Temperature differences along an interface create surface tension gradients, driving fluid motion from regions of low surface tension to high surface tension. This is often observed in boiling, welding, and crystal growth processes.
  • Solutal Marangoni Effect: Concentration gradients of solutes, particularly surfactants, create surface tension differences. This phenomenon plays a crucial role in the behavior of soap films, bubble dynamics, and the stability of emulsions.

C. Critical Micelle Concentration (CMC)

The Critical Micelle Concentration (CMC) is the concentration of surfactants in a solution at which micelles start to form. Beyond this concentration, additional surfactant molecules aggregate into micelles rather than adsorb to the interface.

  • Micelle Formation: At concentrations above the CMC, surfactants spontaneously form micelles, which are aggregates that sequester hydrophobic tails in the center, minimizing their exposure to water.
  • Surface Tension Minimization: Below the CMC, surfactants lower surface tension by adsorbing at the liquid-air interface. Once the CMC is reached, further surfactant addition does not decrease surface tension further, as additional surfactants form micelles.
  • Applications: The concept of CMC is crucial in detergency, where surfactants must reach and exceed the CMC to effectively solubilize oils and greases. It’s also vital in pharmaceutical formulations, where micelles can be used for drug delivery.

Conclusion

Surface Tension measurements provide valuable insights into the materials, impacting fields such as materials science, chemistry, and manufacturing. By utilizing advanced technologies like high-resolution imaging and precise software analysis, these measurements can be conducted with greater accuracy and efficiency. Looking ahead, advancements in technology will lead to more precise measurements, aided by artificial intelligence. The future holds promise for eco-friendly materials and processes, driven by sustainable practices. From pharmaceuticals to consumer products, controlling surface tension will deliver innovative solutions for future challenges.

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